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Crystallographic report: Tetraphenylphosphonium nitratobis (chlorodiphenylstannate)methane, [Ph4P]+[(Ph2ClSn)2CH2 ·NO3]−

✍ Scribed by Klaus Jurkschat; Edward R. T. Tiekink

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
122 KB
Volume
17
Category
Article
ISSN
0268-2605

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Crystallographic report: Bis(tetraphenylphosphonium) bis(dichloro-nitratophenylstannate)methane, [Ph4P+]2 [(PhCl2(NO3)Sn)2CH2]2−
✍ Klaus Jurkschat; Gregor Reeske; Marcus Schürmann; Edward R. T. Tiekink 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 87 KB 👁 1 views

## Abstract Each tin atom of the title compound is five‐coordinate, defined by 2C, 2Cl and 1O atoms, and shows a distorted square pyramidal configuration stabilized by intramolecular Sn· · ·O or Sn· · ·Cl interactions. Both nitrate anions coordinate the tin atoms in a monodentate mode. Copyright ©