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Crystallographic report: N,N′-Dimethylimidazolium tris(selenocyanate) cadmium(II), [Me2Im][Cd(SeCN)3] (Me2Im = N,N′-dimethylimidazolium)

✍ Scribed by Daojie Liu; Dacheng Li

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
72 KB
Volume
17
Category
Article
ISSN
0268-2605

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✦ Synopsis

Abstract

The title structure, [Me~2~Im][Cd(SeCN)~3~] (Me~2~Im = N,N′‐dimethylimidazolium), comprises triply bridged one‐dimensional cadmium‐selenocyanate chains in which the cadmium atoms are octahedrally coordinated within 3__Se__3__N__ geometries. Copyright © 2003 John Wiley & Sons, Ltd.

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In the dinuclear molecule of [(C 5 H 4 N) 3 N] 2 CdCl 2 CdCl 2 , one cadmium is octahedrally coordinated by a Cl 2 N 4 donor set and the other cadmium is tetrahedrally coordinated by four chlorine atoms. The dinuclear units are connected by π -π interactions to give a two-dimensional network.