## Abstract ^13^C chemical shifts of more than fifty bicyclo[3.2.1]octane and bicyclo[2.2.1]heptane derivatives (hydrocarbons, alcohols, ketones and esters) have been determined. The usefulness of ethyl derivatives for the assignment of close ^13^C chemical shifts in bicyclic methyl derivatives is
Crystallographic data for certain derivatives of bicyclo-(2, 2, 1)-heptane
✍ Scribed by R. L. Avoyan; Yu. T. Struchkov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1962
- Tongue
- English
- Weight
- 57 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0022-4766
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📜 SIMILAR VOLUMES
AbstractÐLithium amides induce rearrangement of the title compounds 1 to afford nortricyclanones 4 via a ketocarbene intermediate. Compounds 4 undergo hydride transfer reduction and imino aldol condensation to afford the other observed reaction products.
## Abstract 1,2 __exo__‐Diiodo‐norbornane (**4**) was prepared from norcamphor hydrazone by oxidative iodination and subsequent rearrangement of the 2,2‐diiodo‐bicyclo [2.2.1]heptane (**2**). The stable α‐iodohydrazone **11** was obtained from 1‐iodo‐bicyclo[2.2.1]heptan‐2‐one (**10**), which itsel