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Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)&cjs0811;O Complex

✍ Scribed by Rohde, J.-U.


Book ID
125469374
Publisher
American Association for the Advancement of Science
Year
2003
Tongue
English
Weight
197 KB
Volume
299
Category
Article
ISSN
0036-8075

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Using 'H and "0 NMR spectroscopy it was shown that in the initial stage of the reaction of TiO( acac), (Hacac= acetylacetone) with an excess of Me,COOH in benzene an alkylperoxo complex Ti( acac)2( OOCMe,)OH is formed. The mode of generation of this alkylperoxo complex (via addition of Me,COOH to Ti