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Crystallinity of polymers by x-ray diffraction: a new fitting approach

✍ Scribed by S. Polizzi; G. Fagherazzi; A. Benedetti; M. Battagliarin; T. Asano


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
217 KB
Volume
27
Category
Article
ISSN
0014-3057

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✦ Synopsis


A new method for determining the crystallinity fraction of semi-crystalline polymers from X-ray powder diffraction measurements is presented. Using the scattering of an amorphous sample of the same material and a convenient expression for the disorder factor, the method can lead to precise separation of the crystalline and amorphous contributions by a fitting procedure. In this way, the crystallinity fraction and the disorder factor are automatically obtained. The method is applied to polyethylene terephthalate.


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