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Crystalline-state reaction of cobaloxime complexes accompanying conformational change

✍ Scribed by Yoshio Sasada; Yuji Ohashi

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
882 KB
Volume
126
Category
Article
ISSN
0022-2860

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πŸ“œ SIMILAR VOLUMES

Photophysics of a flexible ligand bridge
Photophysics of a flexible ligand bridged rhodium(I) dimer: An excited state conformational change in a crystalline solid
✍ Richard L. Blakley; Yan Yin; Charles Lloyd; Joel T. Mague; Gary L. McPherson πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 439 KB

The dimeric Rh(I) complex, Rh,(PNP)$+ (where PNP= CH,N [ P(OCH,),],). adopts a flexible "basket" type structure. The solid state phosphorescence from the (C6H&B-salts of the dimeric complex (two crystallographic forms) indicates a thermally activated conformational change in the triplet excited stat