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Crystal structures of α-UF5 and U2F9 and spectral characterizationof U2F9

✍ Scribed by P. Gary Eller; A.C. Larson; J.R. Peterson; D.D. Ensor; J.P. Young


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
465 KB
Volume
37
Category
Article
ISSN
0020-1693

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The U(IV) 6uorides (C 5 H 14 N 2 ) 2 U 2 F 12 ' 5H 2 O (AU1-2) and (NH 4 ) 7 U 6 F 31 have been prepared from the reaction of UO 3 with HF and homopiperazine (C 5 H 12 N 2 ) at 1803C in aqueous media. AU1-2 contains dodecahedral UF 8 units that share two edges to form 1 [UF 4 F 4/2 ] one-dimensional