Crystal structures of the ? alums CsM[SO4]2�12H2O (M = Rh or Ir)
✍ Scribed by Armstrong, Robert S.; Beattie, James K.; Best, Stephen P.; Skelton, Brian W.; White, Allan H.
- Book ID
- 120037931
- Publisher
- The Royal Society of Chemistry
- Year
- 1983
- Tongue
- English
- Weight
- 381 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1472-7773
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Low-temperature, polarized, single-crystal Raman spectra of the a-alum were recorded to CsGa(SeO 4 ) 2 AE 12H 2 O 1000 cm-1. The lattice modes, the external modes of water and the internal modes of [ SeO 4 ] 2-, [ Ga(H 2 O) 6 ] 3' and were assigned. The unpolarized Raman spectrum of was also recorde
## Abstract Low‐temperature, polarized, single‐crystal Raman spectra of the β‐alums CsM(SO~4~)~2~. 12H~2~O (M = Mo or Ru) and their deuterated analogues were recorded between 275 and 1200 cm^−1^. The internal modes of sulphate and [M(OH~2~)~6~]^3+^ and the external modes of water coordinated to the