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Raman spectra of the α-alums CsM(SeO4)2·12H2O (M=Ga, In)

✍ Scribed by Andrew J. Berry; Bradley D. Cole; Robert S. Armstrong

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 107 KB
Volume: 30
Category: Article
ISSN: 0377-0486
DOI: 10.1002/(sici)1097-4555(199901)30:1<73::aid-jrs347>3.0.co;2-0

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✦ Synopsis

Low-temperature, polarized, single-crystal Raman spectra of the a-alum were recorded to CsGa(SeO 4 ) 2 AE 12H 2 O 1000 cm-1. The lattice modes, the external modes of water and the internal modes of [ SeO 4 ] 2-, [ Ga(H 2 O) 6 ] 3' and were assigned. The unpolarized Raman spectrum of was also recorded. [ Cs(H 2 O) 6 ] ' CsIn(SeO 4 ) 2 AE 12H 2 O The alums of Group 13 elements are optically transparent and suitable hosts for a wide range of trivalent hexaaqua cations.

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