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Crystal Structures and Bonding in NOCl, NO2Cl, and NO3Cl

✍ Scribed by Obermeyer, Axel; Borrmann, Horst; Simon, Arndt

Book ID
127229651
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
434 KB
Volume
117
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

Thermal energy rate constants for the re
Thermal energy rate constants for the reactions NO−2 + Cl2 → Cl−2 + NO2, Cl−2 + NO2 → Cl− + NO2Cl, SH− + NO2 → NO−2 + SH, SH− + Cl2 → Cl−2 + SH, and S− + NO2 → NO−2 + S
✍ D.B Dunkin; F.C. Fehsenfeld; E.E. Ferguson 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 258 KB

It is found that charge-transfer of NO, with Cl, is tst at thermal energy. The Cl, ion reacts with NO, to produce Cl-and NOzCI, and SH-charge-transfers rapidly with both Cl, and NOz. From the exothermicitics implied it is deduced that EA (SH)< HA (NOz) < EA (Clz) or EX (Not) = 2.38 + 0.06 eV and EA