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Crystal Structure, Raman Spectroscopy, and Ab Initio Calculations of a New Bialkali Alanate K 2 LiAlH 6

✍ Scribed by Rönnebro, Ewa; Majzoub, Eric H.


Book ID
127222482
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
231 KB
Volume
110
Category
Article
ISSN
0022-3654

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Single crystals of the N,N,N',Wtetramethylethylenediamine (TMEDA) complex 6 of the title compound have been isolated. Compound 6 decomposes in the crystalline state above -20'. From the bond lengths and angles obtained by X-ray crystal-structure analysis (data collected at -707, compound 6 is best d