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Crystal Structure, Phase Transition and Ferroelastic Properties of [N(CH3)4]3[As2Cl9].

✍ Scribed by M. Wojtas; G. Bator; Z. Ciunik

Publisher
John Wiley and Sons
Year
2004
Weight
57 KB
Volume
35
Category
Article
ISSN
0931-7597

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Low-Temperature Phase Transition and Str
Low-Temperature Phase Transition and Structural Relationships of (CH3NH3)3Bi2Cl9
✍ I. Belkyal; R. Mokhlisse; B. Tanouti; K.-F. Hesse; W. Depmeier πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 162 KB

CH 3 NH 3 ) 3 Bi 2 Cl 9 exhibits two phase transitions at T c 1 ‫؍‬ 349 K and T c 2 ‫؍‬ 247 K. The upper transition is probably isomorphous and reveals itself by the anomalous evolution of the lattice parameters. This behavior is explained to be due to increasing thermal motion of the methylammonium