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Raman studies of structural phase transition in [NH2(CH3)2]3Sb2Cl9 (DMACA)

✍ Scribed by A. Miniewicz; J. Lefebvre; R. Jakubas


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
772 KB
Volume
22
Category
Article
ISSN
0377-0486

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Low-Temperature Phase Transition and Str
✍ I. Belkyal; R. Mokhlisse; B. Tanouti; K.-F. Hesse; W. Depmeier πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 162 KB

CH 3 NH 3 ) 3 Bi 2 Cl 9 exhibits two phase transitions at T c 1 ‫؍‬ 349 K and T c 2 ‫؍‬ 247 K. The upper transition is probably isomorphous and reveals itself by the anomalous evolution of the lattice parameters. This behavior is explained to be due to increasing thermal motion of the methylammonium