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Crystal structure of (μ-oxo)bis{aquatris(2-pyridylmethyl)amine}iron(III) perchlorate

✍ Scribed by Bruce R Whittlesey; Zhen Pang; Robert A Holwerda


Book ID
108331722
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
125 KB
Volume
284
Category
Article
ISSN
0020-1693

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✍ Liu, Ying ;Dou, Jianmin ;Li, Dacheng ;Zhang, Xianxi 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 440 KB

The dinuclear Fe^III^ complex in the title compound, [Fe~2~Cl~2~O(C~18~H~18~N~4~)~2~](PF~6~)~2~, lies on a center of inversion. The Fe^III^ atom is chelated by a tetradentate tris(2-pyridylmethyl)amine ligand __via__ four N atoms and further coordinated by one chloride ion and one bridging oxide O a