𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Crystal Structure of Tricarbonyl-[2,3-η:O-σ-(7,7-dimethoxy-5,6-dimethylidenebicyclo[2.2.1]hept-2-ene)]iron

✍ Scribed by Yvan Barbay; Jacques Ioset; Raymond Roulet; Gervais Chapuis

Publisher
John Wiley and Sons
Year
1986
Tongue
German
Weight
229 KB
Volume
69
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

We have reported recently on the synthesis and reactivity of d6 and dX metal carbonyl complexes of 7,7-dimethoxy-5,6-dimethylidenebicyclo[2.2.l]hept-Zene [I]. Among the 30 compounds reported in [l], we have now unambiguous indication that the iron complex 1 and the ruthenium complex 2, originally formulated as [M(CO),(q2olefin)] complexes, are in fact [M(CO),(q' : 0-a-olefin)] complexes as indicated in the Formulae. These are uncommon examples of d8 metal carbonyl complexes bearing an 1 M=Fe(CO), 2 M=Ru(CO), 3 M=Cr(CO), 4 M = Mo(CO), 5 M=W(CO),

📜 SIMILAR VOLUMES

Ironcarbonyl Complexes of 5,6-Dimethylid
Ironcarbonyl Complexes of 5,6-Dimethylidene-7-oxabicyclo[2.2.1]hept-2-ene Derivatives. Synthesis of Substituted Tricarbonyl(ortho-quinodimethane)iron Complexes and 2-Indanones
✍ Edia Bonfantini; Jean-Luc Métral; Pierre Vogel 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 German ⚖ 578 KB

The I-dimethoxymethyl-5,6-dimethylidene-7-oxabicyclo[2.2. I jhept-2-ene (9) has been prepared. On treatment with Fe,(CO),, the endocyclic double bond C(2)=C(3) was coordinated first giving the Corresponding exo-Fe(C0)4 complex 10. The latter reacted with Fe,(CO), and afforded cis-heptacarbonyl-p -[(

Stereoselective Double Friedel-Crafts Ac
Stereoselective Double Friedel-Crafts Acylation of trans-μ-(2,3,6,7-Tetramethylidenebicyclo[3.2.1]octane)bis(tricarbonyliron). Crystal Structure of trans-μ-{(1RS,2RS,3SR,5RS,6SR,7SR)-C,2,3,C-η:C,6,7,C-η-[(Z,Z)-1,1′-(3,7-Dimethylidenebicyclo[3.2.1]octane-2,6-diylidene)di(2-propanone)]}bis(tricarbonyliron)
✍ A. Alan Pinkerton; Dieter Schwarzenbach; Raphy Gabioud; Pierre Vogel 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 German ⚖ 597 KB

305 35. Stereoselective Double Friedel-Crafts Acylation of trans-p -(2,3,6,7-Tetramethylidenebicyclo[3.2.l~octane)bis(tricarbonyIiron).

Condensation of 2,3-Di(methylidene)-7-ox
Condensation of 2,3-Di(methylidene)-7-oxabicyclo[2.2.1]heptane Derivatives into Dicarbonyl[η3:η3-octa-2,6-diene-1,8-diyl]iron Complexes with Nonacarbonyldiiron. Crystal Structure of (1RS,2RS,3RS,4SR,5RS,6SR,1′RS,2′RS,3′RS,4′SR,5′RS,6′SR)-Dicarbonyl-{(2,3,C-η:2′,3′,C-η)-2,2′-ethylene-5,5′,6,6′-tetrakis[(methanesulfonyloxy)-methyl]-3,3′-di(methylidene)-bis[7-oxabicyclo[2.2.1]hept-2-yl]}iron
✍ Shuki Araki; Pierre Vogel; Eric Blanc; Gervais Chapuis; Kurt Schenk 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 German ⚖ 524 KB