Synthesis and Crystal Structures of Cs5N
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Maxim Sokolov; Hideo Imoto; Taro Saito; Vladimir Fedorov
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Article
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1999
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John Wiley and Sons
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German
β 197 KB
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Bis(disulfide) bridged Nb(+4) cluster halide complexes [Nb 2 S 4 X 8 ] 4Β± (X = Cl, Br) were prepared by acid hydrolysis of [Nb 2 S 4 (NCS) 8 ] 4Β± in concentrated aqueous HCl or HBr, solution from which they can be isolated as double salts Cs 5 [Nb 2 S 4 X 8 ]X (X = Cl, 1; X = Br, 2). The crystal st