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Crystal Structure of the T(6-4)C Lesion in Complex with a (6-4) DNA Photolyase and Repair of UV-Induced (6-4) and Dewar Photolesions

✍ Scribed by Andreas F. Glas; Sabine Schneider; Melanie J. Maul; Ulrich Hennecke; Thomas Carell


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
726 KB
Volume
15
Category
Article
ISSN
0947-6539

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In(C 6 F 5 ) 3 ´CH 3 CN and In(C 6 F 5 ) 3 ´glyme were synthesized from InCl 3 and Cd(C 6 F 5 ) 2 in CH 3 CN or glyme in 43% and 35% yield, respectively. Replacement of CH 3 CN or (C 2 H 5 ) 2 O by DMAP yielded the corresponding 1 : 1-adduct. [PNP][In(C 6 F 5 ) 4 ] was best prepared from the corres