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Crystal structure of R(–)–1–Tosyl–2–methylpyrrolidine

✍ Scribed by Vivek K. Gupta; Dr.; Prof. K. N. Goswami; D. K. Gupta; K. K. Bhutani

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
441 KB
Volume
30
Category
Article
ISSN
0232-1300

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✦ Synopsis

Crystal structure of R( -)-1-Tosyl-2-methylpyrrolidine

The crystal structure of R( -)-1-tosyl-2-methylpyrrolidine has been determined by X-ray structure analysis. The compound crystallizes in the monoclinic space group P2, with cell parameters a = 7.858( l), b = 14.929(6), c = 11.128(1) A, p = 105.42(1) ' . The structure has been solved by direct methods and relined to R = 0.046. There are two crystallographically independent molecules A and B in the asymmetric unit. The pyrrolidine ring of molecule A is disordered with atom C4 occupying two possible sites. The S atom has a distorted tetrahedral coordination in both the molecules. Two bifurcated hydrogen bonds are observed. Molecules are held together by hydrogen bonds.

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