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Crystal Structure of Bis-(1-ethyl-2-quinolyl)-phosphamethinecyanine Perchlorate

✍ Scribed by Dr. I. Kawada; Dr. R. Allmann

Publisher: John Wiley and Sons
Year: 1968
Tongue: English
Weight: 129 KB
Volume: 7
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.196800691

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✦ Synopsis

It might, however, also be the case that the SH groups involved in the enzyme action are protected by binding of the substrate to some other group in the active center before reaction with the relatively large ASPM molecule. We have therefore studied, as a model reaction, the reaction of pyruvate ( I ) , R -= CH3, andoftrimethylpyruvate(I),R = C(CH3)3, with cysteine, using spectroscopy in the region of the n +n*transition at pH 7.4; we found that the extinction of a pyruv-

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