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Manganese Oxidation Catalysts with 2-(2′-Hydroxyphenyl)oxazoline Ligands: Catalyst Intermediates and Degradation Products − Crystal Structure of Bis[{2-(2′-oxazolinyl)phenolato}bis(1-methylimidazole)manganese(III)] Perchlorate

✍ Scribed by Marcel Hoogenraad; Huub Kooijman; Anthony L. Spek; Elisabeth Bouwman; Jaap G. Haasnoot; Jan Reedijk


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
117 KB
Volume
2002
Category
Article
ISSN
1434-1948

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The synthesis and structural characterization of manganese, iron, and cobalt complexes of bis[di(2-pyridyl)methyl]amine (bdpma) were investigated. The bdpma ligand can give rise to mono-or dimeric complexes. Moreover, bdpma can undergo oxidative degradation leading to 1,3,3-tris(2-pyridyl)-3Himidazo