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Crystal structure of phenyl-substituted cyclopentenes

✍ Scribed by Franco Benetollo; Vilma Busetti; Franco Marcuzzi


Book ID
110275449
Publisher
Springer
Year
1999
Tongue
English
Weight
101 KB
Volume
29
Category
Article
ISSN
1572-8854

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The osmylation of several 3-substituted cyclopentenes has been studied. A preference for 0~04 addition syn to an allylic CHR2 substituent is observed. By contrast, bulkier substiments of type CMeR, give rise to a striking reversal of selectivity. These results are interpreted in terms of the stereod