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Crystal structure of dicyclohexylammonium succinatotriphenylstannate at 138 K

✍ Scribed by Seik Weng Ng; V. G. Kumar Das; Gaoyi Xiao; Dick Van Der Helm; Jaroslav Holec̆ek; Antonín Lyc̆ka

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
271 KB
Volume
2
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

Dicyclohexylammonium succinatotriphenylstannate, synthesized by condensing [(c‐C~6~H~11~)~2~NH~2~] [HO~2~C(CH~2~)~2~CO~2~] with (C~6~H~5~)~3~SnOH, has a zig‐zag structure consisting of polymeric chains in which planar triphenyltin cations (Σ C–Sn–C = 360.0(2)°) are axially linked by succinato dianions (Sn–O = 2.214(2) Å; O–Sn–O = 172.52(6)°); the dicyclohexylammonium cations surround the chain and are hydrogen‐bonded to the acyl oxygens of the ligand (N…O = 2.829(3) Å). The stannate is four‐coordinate in CDCl~3~ solution.

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