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Crystal Structure of 1,1,4,4-Tetrafluorocyclohexane at 95 K

✍ Scribed by Jack D. Dunitz; W. Bernd Schweizer; Paul Seiler

Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
271 KB
Volume
66
Category
Article
ISSN
0018-019X

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✦ Synopsis

The crystal structure of 1,1,4,4‐tetrafluorocyclohexane has been determined from X‐ray diffraction measurements at 95 K. Internal motion of the CF~2~‐group can be discerned from analysis of the atomic vibration tensors. The pattern of bond lengths suggests that an anomeric‐effect type of interaction between antiperiplanar C,C‐ and C,F‐bonds (as well as between C,H‐ and C,F‐bonds) may be operative in this molecule.

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