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Crystal structure of Co(3-pic)2Cl2and thermal behaviour of a new complex, Co(py)(3-pic)Cl2

✍ Scribed by Dariusz Wyrzykowski; Emilia Styczeń; Zygmunt Warnke; Rafał Kruszyński


Publisher
Springer
Year
2006
Tongue
English
Weight
323 KB
Volume
31
Category
Article
ISSN
0340-4285

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✍ Mami Mikami; Michiko Konno; Yoshihiko Saito 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 367 KB

Tne wsta! structure of the spin crossover complex [re(l-pic)l] CIZ -EtOH in its high spin stare (798. 150 K) and ION skin smtc (90 6) has been determined. The cry~ak are monoclinic. PZl/c \xith Z=4 in. the two spin states. Pronounced clung= in tire Fe-X bond distance (Z-I% A for high spin. 2.013 X f