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Crystal Structure of CF3SNSO-AsF5

✍ Scribed by Brosius, Axel ;Haas, Alois

Publisher
Wiley (John Wiley & Sons)
Year
1995
Tongue
English
Weight
126 KB
Volume
128
Category
Article
ISSN
0009-2940

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Synthesis and Raman Spectra of [Nd(XeF2)n](AsF6)3 (n=3, 2.5) and Crystal Structure of [Nd(XeF2)2.5](AsF6)3
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The reaction between Nd(AsF 6 ) 3(solv) and excess of XeF 2(solv) in anhydrous HF (aHF) yields compounds of the type [Nd(XeF 2 ) n ] (AsF 6 ) 3 (n ‫؍‬ 3, 2.5). The 5rst compound is very soluble in aHF while the latter crystallizes from the saturated solution in aHF. Pink needles [Nd(XeF 2 ) 2.5 ] (A