The anisotropic ESR spectra of the CFsX-radical anions (X = Cl, Br, I) have been observed following 7 irradiation at 77 K of solid solutions containing up to 5 mole % of the CF3X parent compound in tetramethylsilane (TMS), neopentane, and 2-methyltetrahydrofuran. The resolution of the line component
โฆ LIBER โฆ
Crystal Structure of CF 3 I(Cl)F
โ Scribed by Minkwitz, Rolf; Berkei, Michael
- Book ID
- 120546908
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 30 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The haloacyltris(trifluoromethyl)borate anions [(CF~3~)~3~BC(O)Hal]^โ^ (Hal=F, Cl, Br, I) have been synthesized by reacting (CF~3~)~3~BCO with either MHal (M=K, Cs; Hal=F) in SO~2~ or MHal (M=[__n__Bu~4~N]^+^, [Et~4~N]^+^, [Ph~4~P]^+^; Hal=Cl, Br, I) in dichloromethane. Metathesis react