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Crystal Structure, Chemical Bonding, and Phase Relations of the Novel Compound Co4Al7+xSi2-x (0.27 ≤ x ≤ 1.05).

✍ Scribed by Klaus W. Richter; Yurii Prots; Yuri Grin


Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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✍ Riadh Marzouki; Abderrahmen Guesmi; Ahmed Driss 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 22 KB

The Novel Arsenate Na 4 Co 7-x Al 2/3x (AsO 4 ) 6 (x = 1.37): Crystal Structure, Charge--Distribution and Bond-Valencesum Investigations. -Single crystals of the new title compound are prepared by solid state reaction of Na2CO3, Co(OAc)2•4H2O, and As2O3 in air (675→1153 K, 3 d). Na4Co5.63Al0.91(AsO4