Synthesis and Crystal Structure of the γ-Modifications of US2 and USe2. -Microcrystalline powders of γ-UX2 (X: S, Se) are prepared from U3X5 and X at 600 and 800 K, resp., in evacuated silica ampoules by a presumably topotactic reaction. γ-USe2 is also formed from . alpha.-USe2 at 4 GPa and 773 K.
✦ LIBER ✦
Crystal structure and properties of the uranium chalcogenides α-US2 and α-USe2
✍ Scribed by H. Noel; J.Y. Le Marouille
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 386 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-4596
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known, but single crystals of Ͳ USe2 have been obtained, and the structure of this compound has been determined The uranium diselenide  USe 2 and the seleno-telluride USe 1.76 Te 0.24 crystallize in the orthorhombic system, with the recently (9). PbCl 2 type, space group Pnma, and lattice constant