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Crystal Structure and Magnetic Properties of Gd 2 ([18]crown-6) 2 (OH) 2 (CH 3 CN) 2 [Ni(dmit) 2 ] 4 Complex Having f- and π-Spins

✍ Scribed by Nishihara, Sadafumi; Akutagawa, Tomoyuki; Hasegawa, Tatsuo; Nakamura, Takayoshi


Book ID
127240957
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
130 KB
Volume
42
Category
Article
ISSN
0020-1669

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Two Polymorphs of (Anilinium)(18-Crown-6
✍ Sadafumi Nishihara; Tomoyuki Akutagawa; Tatsuo Hasegawa; Shigeki Fujiyama; Toshi 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 341 KB

Two polymorphs of monovalent [Ni(dmit) 2 ] À (dmit 2À =2thioxo-1,3-dithiole-4,5-dithiolate) crystals A and B, (anilinium)(18-crown-6)[Ni(dmit) 2 ], were prepared, and the structure and magnetic properties were investigated. In these crystals, the [Ni(dmit) 2 ] À molecules form dimers, which arranged