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Crystal Structure and Magnetic Behaviour of the New Gadolinium Carboxylates Gd2(ClF2CCOO)6(hypy)2, Gd2(F3CCOO)6(hypy)2, Gd2(F2HCCOO)6(hypy)2 and Gd2(Cl2HCCOO)6(H2O)2(hypy)2

✍ Scribed by Daniela John; Werner Urland


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
401 KB
Volume
2006
Category
Article
ISSN
1434-1948

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πŸ“œ SIMILAR VOLUMES


Crystal Structure and Magnetic Behaviour
✍ Daniela John; Werner Urland πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 161 KB

## Abstract Single crystals of the title compound have been obtained by reaction of Gd~3~(ClH~2~CCOO)~9~(H~2~O)~5~ with 2,2′‐bipyridyl (bipy) in a solution of ethanol and water. Gd~2~(ClH~2~CCOO)~6~(bipy)~2~ crystallises in the triclinic space group __P__$\bar {1}$ (__Z__ = 2) with __a__ = 959.5(3)

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3+ . -The phosphors Ca6Gd2-xTbxNa2(PO4)6F2 show strong absorption in the vacuum UV (VUV) range and have intense emission upon 172 nm excitation, while Ca6La2-xTbxNa2(PO4)6F2 phosphors exhibit weaker absorption in the VUV range. The emission color of both phosphors can be tuned from blue to yellow-gr

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