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Crystal structure and magnetic behavior of the new gadolinium complex compound [NH3C2H5][Gd(Cl2HCCOO)4]

✍ Scribed by Alexander Rohde; Werner Urland

Book ID
116598951
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
193 KB
Volume
408-412
Category
Article
ISSN
0925-8388

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πŸ“œ SIMILAR VOLUMES

Crystal Structure and Magnetic Behaviour
Crystal Structure and Magnetic Behaviour of the New Gadolinium Complex Compound Gd2(ClH2CCOO)6(bipy)2
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## Abstract Single crystals of the title compound have been obtained by reaction of Gd~3~(ClH~2~CCOO)~9~(H~2~O)~5~ with 2,2′‐bipyridyl (bipy) in a solution of ethanol and water. Gd~2~(ClH~2~CCOO)~6~(bipy)~2~ crystallises in the triclinic space group __P__$\bar {1}$ (__Z__ = 2) with __a__ = 959.5(3)

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The preparation, crystal structure and magnetic properties of the title compound, (1,3-xylylenediammonium)auqatrichlorocuprate(II) chloride hydrate, have been determined. It is monoclinic, space group P2 1 /c, with a=12.711(2), b= 6.122(1), c=19.175(5) A , and i =96.72(2)Β°with V= 1481.6(5) A , 3 for