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Crystal structure and EPR studies of (cinchonineH2)2(CdCl4)(Cd/CuCl4) crystals with thermochromic and Jahn–Teller effect

✍ Scribed by A. Wesełucha-Birczyńska; B.J. Oleksyn; J. Śliwiński; J. Goslar; W. Hilczer; S.K. Hoffmann


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
375 KB
Volume
751
Category
Article
ISSN
0022-2860

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An exploration of the cadmium-L system under hydrothermal condition, has led to the isolation of a novel framework {[Cd(L) 0.5 (H 2 O) 3 ]} n (1) (H 4 L = 4,4'-diazenediyldiphthalic acid). Single-crystal X-ray analysis reveals that it crystallizes in the triclinic space group P-1. a = 5.746(3) Å, b