Magnetic properties and electronic struc
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L.B. Dugad; D.V. Behere; V.R. Marathe; S. Mitra
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Article
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1984
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Elsevier Science
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English
⚖ 391 KB
The average magnetic susceptibility 0-2-100 K) and magnetisation (105-15500 Oe at 4.2 IQ of two perchlorato manganese(lII) porphyrins establish them to be high-spin, in contrast to the "anomalous" behaviour of analogous iron(M) porphyrins An explanation of the origin of the zero-field splitting in h