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Crystal structure and electrochemical properties of the supramolecular compound [Himi]6[As2Mo18O62]·11H2O

✍ Scribed by Yanyan Yang; Lin Xu; Liping Jia; Guanggang Gao; Fengyan Li; Xiaoshu Qu; Yunfeng Qiu

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
260 KB
Volume
42
Category
Article
ISSN
0232-1300

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✦ Synopsis

A supramolecular compound, [Himi] 6 [As 2 Mo 18 O 62 ]•11H 2 O (1) (imi = imidazole), has been synthesized and characterized by single crystal X-ray analysis, IR spectra, thermal gravimetric analysis, electrochemical and elemental analysis. The crystals are monoclinic, P 2(1)/n, a = 14.9529(8) Å, b = 20.9521(11) Å, c = 25.2464(13) Å, β = 93.8130(10)º, V = 7892.1(7) Å 3 , Z = 4. X-ray diffraction indicated that protonated imidazole cation and polyanion were linked together through electrostatic interactions and intermolecular forces (hydrogen bonding).

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v