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Crystal Structure and Electrochemical Properties of the Supramolecular Compound [Himi]6 [As2Mo18O62]×11H2O.

✍ Scribed by Yanyan Yang; Lin Xu; Liping Jia; Guanggang Gao; Fengyan Li; Xiaoshu Qu; Yunfeng Qiu

Publisher
John Wiley and Sons
Year
2007
Weight
16 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Crystal structure and electrochemical pr
Crystal structure and electrochemical properties of the supramolecular compound [Himi]6[As2Mo18O62]·11H2O
✍ Yanyan Yang; Lin Xu; Liping Jia; Guanggang Gao; Fengyan Li; Xiaoshu Qu; Yunfeng 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB

A supramolecular compound, [Himi] 6 [As 2 Mo 18 O 62 ]•11H 2 O (1) (imi = imidazole), has been synthesized and characterized by single crystal X-ray analysis, IR spectra, thermal gravimetric analysis, electrochemical and elemental analysis. The crystals are monoclinic, P 2(1)/n, a = 14.9529(8) Å, b

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From Molecular to Two-Dimensional Anders
From Molecular to Two-Dimensional Anderson Polyoxomolybdate: Synthesis, Crystal Structure, and Thermal Behavior of [{Ni(H2O)4}2{Ni(OH)6Mo6O18}]·4H2O and [Ni(H2O)6][Ag2{Ni(OH)6Mo6O18}]·8H2O
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## Abstract Two 2D Anderson polyoxomolybdate‐based compounds, [{Ni(H~2~O)~4~}~2~{Ni(OH)~6~Mo~6~O~18~}]·4H~2~O (1) and [Ni(H~2~O)~6~][Ag~2~{Ni(OH)~6~Mo~6~O~18~}]·8H~2~O (2), were synthesized and characterized by elemental analysis, IR spectroscopy, SEM, and single‐crystal XRD. Their thermal behavior