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Crystal structure and characterization of [Co(saccharinate)2(L1)(H2O)2]nsolvate: A new microporous coordination polymer generated from 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (L1) and [Co(saccharinate)2·4H2O]·2H2O

✍ Scribed by Harvey Davis; LeRoy Peterson; Andrea M. Goforth; Mark D. Smith; Paul Zhang; Hans-Conrad zur Loye


Book ID
111591774
Publisher
Springer
Year
2004
Tongue
English
Weight
524 KB
Volume
34
Category
Article
ISSN
1572-8854

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Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a