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Crystal structure and thermal properties of novel Co(II) complexes with 2,6-pyridine-dicarboxylate containing infinite one-dimensional chain: [CoL1(H2O)4][Co(pydc)2]·2H2O and [Co(H2O)6]×[Co(pydc)2]L2·H2O (L1= 1,3-bis(4-pyridyl)propane, L2= 3-amino-1H-1,2,4-triazole, pydc = 2,6-pyridine-dicarboxylic acid)

✍ Scribed by M. -S. Zhang; B. -W. Sun; R. -B. Fang; Q. -H. Zhao

Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
175 KB
Volume
51
Category
Article
ISSN
0022-4766

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Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a