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Crystal habit of a novel host-guest complex composed of 1,1,2,2-tetrakis(4-hydroxyphenyl)ethane and 5-chloro-2-methyl-4-isothiazolin-3-one

✍ Scribed by Hiroshi Suzuki; Hideo Takagi; Ryu Sato


Book ID
104257332
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
271 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


The crystal structure of the inclusion complex of 1,1,2,2-tetrakis(4-hydrox'yphenyl)ethane (TEP) with 5-chloro-2-methyl-4-isothiazolin-3-one (CMI) is duo"acterized as layered molecular sheets composed of hydrogen-bonded polyphenol chains. CMI molecules bind to TEP by SmJr electrostatic interaction and by O-HmO=C hydrogen bonding to form a crystalline complex of TEP°2CMI, which behaves as a unique host with chfferent recognition from TEP.


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