Crystal-field splitting in the M11,111 spectra of Co(II) compounds
β Scribed by R.G. Hayes
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 249 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Reccned 5 October I98 I \i'c hwzmlyzcd part of Ihc hl,, ,,t absorption spr'clra of the compounds CoF2, CoCI., 1 CoBr2. Co(aca~)~ as due fo [he rxystJl-field %ph~un~ oi 3 'C state arkmg from the conliguration 3ps3d8.
π SIMILAR VOLUMES
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The apparent spin-orbit splitting of 4d energy IeveIs in cadmium metal and cadmium dimethyl is discussed in terms of crystal-fieId and band-broadening models. The use of nuclear field gradients from Mossbauer and NQR measurements in distinguisbing between these t\vo models is evaluated by CNDO calcu
It is proposed that the splitting observed in the low temperature reflection spectrum of bis-pamtoluene sulfonate diacetyiene polymer single crystals is a manifestation of site splitting in a Frenkel exciton transition. Possible origins of the site splitting enemy are discussed\_