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Crystal engineering: a solid state Diels-Alder reaction

โœ Scribed by Radha Kishan, K. V.; Desiraju, Gautam R.


Book ID
126097899
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
280 KB
Volume
52
Category
Article
ISSN
0022-3263

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A resin-bound furan has been efficiently synthesized from Merrifield resin. This new polymer reacts with an acetylenic dienophile to afford a thermally stable Diels-Alder adduct. Transformation of the adduct by Michael reaction with thiophenol has allowed an easy retro Diels-Alder reaction. This 'sa