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Diels-Alder reaction volumes in the solid state and solution

โœ Scribed by V. D. Kiselev; G. G. Iskhakova; E. A. Kashaeva; L. N. Potapova; A. I. Konovalov

Publisher
Springer
Year
2004
Tongue
English
Weight
247 KB
Volume
53
Category
Article
ISSN
1573-9171

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๐Ÿ“œ SIMILAR VOLUMES

Evidence of volume contraction in the tr
Evidence of volume contraction in the transition state of the diels alder reaction
โœ Kazuyoshi Seguchi; Akira Sera; Kazuhiro Maruyama ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 173 KB

In the Diels Alder reactron the adduct with the endo conflguratlon ~3, m general, 2) much preferred over the adduct having the exo conflguratlon. wooaward

Solid state photochemistry for fullerene
Solid state photochemistry for fullerene functionalization: Solid state photoinduced electron transfer in the Diels-Alder reaction with anthracenes
โœ Koichi Mikami; Shoji Matsumoto; Takayuki Tonoi; Yasutaka Okubo; Tomoyoshi Suenob ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 234 KB

The Diels-Alder adducts of C60 with 9-methylanthracene were obtained selectively through photoinduced electron transfer process in solid state as an environmentally benign process in solvent-free system.

Endo and exo transition states in the Di
Endo and exo transition states in the Diels-Alder reaction
โœ William C. Herndon; Lowell H. Hall ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 278 KB

We have recently determined kinetic parameters for the unimolecular Diels-Alder retrogressions of exe and w-dicyclopentadiene to monomer (1). The activation enthalpies and entropies are aH f (E) 37.4 2 0.3 kcal/mole, hSS (E) + 1.1 2 0.6 e.u., hH + (&) 33.0 2 0.5 kcal/mole, and hSS (endo) \_ -1.9 +

Selective diels-alder reactions in aqueo
Selective diels-alder reactions in aqueous solutions and suspensions
โœ Ronald Breslow; Uday Maitra; Darryl Rideout ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

## Diels-Alder reactions show high endo/exo selectivities in aqueous suspensions. We have described 1 the very large rate accelerations which occur when some common Diels-Alder reactions are performed in water solution. The principal effect was ascribed to hydrophobic association of the diene wit