✦ LIBER ✦

Crystal and molecular structures of two nickel maleonitriledithiolate complexes containing 1-methyl-3-(2′-nitryl-4′-bromo-benzyl)-imidazolium cations

✍ Scribed by Dongbin Dang; Yan Bai; Lili Wen; Zhengfang Tian; Yizhi Li; Qingjin Meng

Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 194 KB
Volume: 753
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2005.05.051

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✦ Synopsis

Two new ion-pair complexes, [NO

Zmaleonitriledithiolate, have been synthesized and characterized by elemental analysis, IR spectroscopy, UV-visible spectroscopy and X-ray crystallography. The single crystal structure analyses show that in the dianionic complex 1 cations and anions are intermingled each other and stacked along the c-axis with an ACCACC-type repeat unit, whereas the monoanionic complex 2 forms a well-segregated stacking column structure in the solid state.

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