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Crystal and Molecular Structure of Rubidium Peroxodicarbonate Rb2[C2O6]

✍ Scribed by Robert E. Dinnebier; Sascha Vensky; Martin Jansen

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
179 KB
Volume
9
Category
Article
ISSN
0947-6539

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✦ Synopsis

Abstract

We report the crystal structure of rubidium peroxodicarbonate, which was synthesized by electrocrystallization at T=257 K, from laboratory X‐ray powder diffraction data. The compound crystallizes in the monoclinic space group P__2~1~/c with four formula units per unit cell and cell parameters of a=7.9129(1), b=10.5117(1), c=7.5559(1) Γ…, Ξ²=102.001(1)Β°, and V=614.75(1) Γ…^3^. The packing can be considered as a strongly distorted CsCl type of structure. The conformation of the peroxodicarbonate anion was found to be planar (C~2__h~ symmetry), in contrast to the staggered conformation of the peroxodicarbonate anion in the respective potassium peroxodicarbonate. The different conformation is attributed to packing effects.

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