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Crystal and molecular structure of (N,N'-dimethyl-2,11-diaza[3.3](2,6)pyridinophane)copper dichloride monohydrate complex

✍ Scribed by Fronczek, Frank R.; Mamo, Antonino; Pappalardo, Sebastiano


Book ID
126062635
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
446 KB
Volume
28
Category
Article
ISSN
0020-1669

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Tridentate coordination of the potentially tetradentate ligand relevance of the tridentate coordination mode of the ligand is discussed with respect to its intermediacy in the reaction N, NЈ-dimethyl-2,11-diaza[3.3](2,6)pyridinophane (L-N 4 Me 2 ) has been structurally established in the tricarbonyl

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The properties of the tetraazamacrocyclic compound N,N 'dimethyl-2,11 -diaza[ 3,3] (2,G)pyridinophane (L-N4Mez) as a ligand for some selected metal chlorides have been examined. The crystal structure of the uncoordinated ligand reveals a syn chair-chair conformation. In solution, the ligand displays