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Tridentate Coordination Mode of N,N′-Dimethyl-2,11-diaza[3.3](2,6)pyridinophane in a Tricarbonylmolybdenum(0) Complex

✍ Scribed by Harald Kelm; Hans-Jörg Krüger

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 218 KB
Volume: 1998
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199810)1998:10<1381::aid-ejic1381>3.0.co;2-8

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✦ Synopsis

Tridentate coordination of the potentially tetradentate ligand relevance of the tridentate coordination mode of the ligand is discussed with respect to its intermediacy in the reaction N, NЈ-dimethyl-2,11-diaza3.3pyridinophane (L-N 4 Me 2 ) has been structurally established in the tricarbonylmolyb-mechanism for the formation of cis octahedral metal complexes containing tetradentate 2,11-diaza3.3-denum(0) complex [Mo(L-N 4 Me 2 )(CO) 3 ]. The fluxional behavior of the coordinated tetraazamacrocyclic ligand is pyridinophane derivatives as ligands. demonstrated by a variable-temperature 1 H-NMR study. The

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