Crystal and molecular structure of bis(tetrathiafulvalene) bis(maleonitrile-1,2-dithiolato)nickelate(II)
✍ Scribed by C. Mahadevan
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 336 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1572-8854
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## Experimental Crystal data (C 26 H 21 NP) 2 [Ni(C 4 N 2 S 2 ) 2 ] M r = 1095.89 Monoclinic, P2 1 =n a = 19.158 (4) A b = 14.956 (3) A c = 19.598 (4) A ˚ = 108.785 (4) V = 5316.3 (19) A ˚3 Z = 4 Mo K radiation = 0.63 mm À1 T = 298 (2) K 0.34 Â 0.22 Â 0.15 mm Data collection Bruker SMART APEX CCD
In the title compound, (C 12 H 10 Br 2 N) 2 [Ni(C 4 N 2 S 2 ) 2 ], the Ni II atom of the anion lies on an inversion centre and exhibits a square-planar coordination geometry. The benzene and pyridine rings of the cation make a dihedral angle of 74.6 (3) . The cations (C1 and C2) and anions (A) are a