𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis[1-(3-cyanobenzyl)triphenylphosphonium] bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickelate(II)

✍ Scribed by Ni, Chun-lin ;Zhou, Jia-rong ;Hou, Yong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
947 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

Experimental

Crystal data (C 26 H 21 NP) 2 [Ni(C 4 N 2 S 2 ) 2 ] M r = 1095.89 Monoclinic, P2 1 =n a = 19.158 (4) A b = 14.956 (3) A c = 19.598 (4) A ˚ = 108.785 (4) V = 5316.3 (19) A ˚3 Z = 4 Mo K radiation = 0.63 mm À1 T = 298 (2) K 0.34 Â 0.22 Â 0.15 mm Data collection Bruker SMART APEX CCD diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 2004) T min = 0.834, T max = 0.912 25624 measured reflections 9356 independent reflections 6235 reflections with I > 2(I) R int = 0.076 Refinement R[F 2 > 2(F 2 )] = 0.061 wR(F 2 ) = 0.139 S = 1.09 9356 reflections

📜 SIMILAR VOLUMES

Bis[(3-fluorobenzyl)triphenylphosphonium
Bis[(3-fluorobenzyl)triphenylphosphonium] bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickel(II)
✍ Liao, Quan-Bin ;Liu, Ming-Guo ;Ni, Chun-Lin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 495 KB

In the title salt, (C~25~H~21~FP)~2~[Ni(C~4~N~2~S~2~)~2~], the Ni^II^ ion lies on an inversion centre and the [Ni(mnt)~2~]^2−^ anion (mnt is maleonitriledithiolate) exhibits a square-planar coordination geometry. The (3-fluorobenzyl)triphenylphosphonium cation adopts a conformation in which the four

Bis(2-amino-1-benzylpyridinium) bis(2,2-
Bis(2-amino-1-benzylpyridinium) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
✍ Hou, Yong ;Huang, Qian ;Zuo, Hongrong ;Ni, Chunlin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 715 KB

, was obtained by the direct reaction of NiCl 2 Á6H 2 O, K 2 imnt and (Bz2NH 2 py) + ÁBr À in water. The Ni II ion lies on an inversion centre and the asymmetric unit contains a (Bz2NH 2 py) + cation and one-half of the Ni(imnt) 2 2À anion. The Ni II ion adopts a square-planar coordination geometry.

Bis[1-(3,5-dibromobenzyl)pyridinium] bis
Bis[1-(3,5-dibromobenzyl)pyridinium] bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickelate(II)
✍ Liao, Quan-Bin ;Liu, Ming-Guo ;Ni, Chun-Lin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 498 KB

In the title compound, (C 12 H 10 Br 2 N) 2 [Ni(C 4 N 2 S 2 ) 2 ], the Ni II atom of the anion lies on an inversion centre and exhibits a square-planar coordination geometry. The benzene and pyridine rings of the cation make a dihedral angle of 74.6 (3) . The cations (C1 and C2) and anions (A) are a

Bis(piperidinium) bis(1,2-dicyanoethene-
Bis(piperidinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickel(II)
✍ Hou, Yong ;Zuo, Hongrong ;Huang, Qian ;Ni, Chunlin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 452 KB

The title compound, (C~5~H~12~N)~2~[Ni(C~4~N~2~S~2~)~2~], is a new [Ni(mnt)~2~]^2−^ salt (mnt^2−^ is 1,2-dicyanoethene-1,2-dithiolate) with piperidinium [(PIH)^+^] cations. The Ni^II^ ion lies on an inversion centre and the asymmetric unit contains a (PIH)^+^ cation and one half of the [Ni(mnt)~2~]^

Bis­[1-(3-cyano­benzyl)-3-methyl­pyrazin
Bis­[1-(3-cyano­benzyl)-3-methyl­pyrazinium] bis(1,2-di­cyano­ethene-1,2-di­thiol­ato)­nickel(II)
✍ Tian, Zheng-Fang ;Li, Yi-Zhi ;Meng, Qing-Jin ;Liu, San-Hui ;Ji, Xing-Xiang 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 312 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.055 wR factor = 0.133 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.