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Crystal and molecular structure of 1,1,4,4-tetramethyl-1, 4-digermanium cyclohexadiene-2,5

✍ Scribed by N. G. Bokii; G. N. Zakharova; Yu. T. Struchkov


Publisher
SP MAIK Nauka/Interperiodica
Year
1968
Tongue
English
Weight
948 KB
Volume
8
Category
Article
ISSN
0022-4766

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1,4-dicarbonyl-2,5-cyclohexadiene
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## Abstract The mechanism of the photolysis of [2.2]paracyclophane‐1,10‐dione (9) was investigated in solution and in argon matrices. The first step of the photolysis involves α‐cleavage of the cyclophane yielding a diradical 11 which could be trapped by ethanol. In argon at 10 K the diradical rapi