𝔖 Bobbio Scriptorium
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Cryptophycin Synthesis

✍ Scribed by Marcus A. Tius

Publisher
John Wiley and Sons
Year
2004
Weight
46 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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AbstractÐA total synthesis of cryptophycin 337 (1-aza-cryptophycin 1, 2), an analogue of the potent antitumor antibiotic cryptophycin 1 (1), is described. Cryptophycin 337 was unstable and underwent an unexpected skeletal rearrangement. (R)-Mandelic acid was used as the sole source of asymmetry for