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Cryochemical studies. 3. EPR studies of the reaction of group IB metal atoms with arenes at 77 K with a rotating cryostat

โœ Scribed by Buck, A. J.; Mile, B.; Howard, J. A.


Book ID
127294736
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
939 KB
Volume
105
Category
Article
ISSN
0002-7863

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Using a relative rate technique the reactions of chlorine and fluorine atoms with CF3CHO have been determined to proceed with rate constants of (1.8 % 0.4) x and (2.7 2 0.1) x lo-" cm3 molecule-' s-', respectively. Experiments were performed a t 295 ? 2 K and 700 torr total pressure of nitrogen. The